Cyclooctatetraene: A Bioactive Cubane Paradigm Complement
نویسندگان
چکیده
منابع مشابه
Bis-cyclooctatetraene tripalladium sandwich complexes.
We report synthesis and structural characterization of bis-cyclooctatetraene trinuclear palladium sandwich complexes. The non-planar cyclooctatetraene ligands flank an isosceles Pd3 triangle, which is supported by one equatorial ligand.
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متن کاملRole of bifurcation in the bond shifting of cyclooctatetraene
The present study of the cyclooctatetraene potential energy surface shows the presence of a bifurcation (valley ridge inflection point) in the intrinsic reaction coordinate path between the two transition states of D(8h) and D(4h) symmetries. This result is of capital importance for the correct understanding of the bond shifting and ring inversion processes in this compound.
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2019
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201806277